Oxidative Coupling of an Anionic Gallium(I) Carbene Analogue: Synthesis and Structural Characterization of an Unprecedented π-Cyclopentadienyl-Bridged Digallane Complex
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An unprecedented π-cyclopentadienyl-bridged digallane complex, [{Ga[N(Ar)C(H)]2}2{μ-CpK(tmeda)2}] (Ar = C6H3Pri2-2,6), incorporating the first structurally characterized π-interaction with a Ga(II) center, results from the oxidative coupling of an anionic gallium(I) heterocycle with cyclopentadienylthallium(I). This compound can be regarded as an intermediate in the nucleophilic attack of a digallane by the Cp- anion.
创建时间：
2004-10-11
