Diastereoselective Pd-Catalyzed Anomeric C(sp3)–H Activation: Synthesis of α‑(Hetero)aryl C‑Glycosides
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Anomeric C–H bond activation is an unsolved long-standing synthetic challenge. Herein, we report a diastereoselective Pd-catalyzed anomeric C(sp3)–H activation methodology that allows the synthesis of elusive C-(hetero)aryl glycosides with an exclusive α-selectivity.
