Synthesis of Neutral Mixed Sandwich CH<sub>2</sub>-SiR<sub>2</sub> Bridged [2]Cobaltoarenophanes from the Dilithiation of Cb*CoCp [Co(η<sup>4</sup>-C<sub>4</sub>Me<sub>4</sub>)(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)]
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The dilithiation of [Co(η4-C4Me4)(η5-C5H5)] to give [Co(η4-C4Me3CH2Li)(η5-C5H4Li)]·PMDETA and the subsequent synthesis and characterization of the CH2-SiR2-bridged [2]cobaltoarenophanes is reported. This is the first development in the chemistry of neutral 18-electron metalloarenophanes featuring a group 9 transition metal.
创建时间：
2007-12-03
