Evidence for a Transition State Model Compound of In-Plane Vinylic S<sub>N</sub>2 Reaction
收藏NIAID Data Ecosystem2026-03-06 收录
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To isolate a transition state model compound of an in-plane vinylic SN2 reaction, vinyl bromide 6 bearing a newly synthesized tridentate ligand derived from 1,8-dimethoxythioxanthen-9-one (5) was prepared as a precursor. Although irradiation of 6 gave demethylated benzofuran 12, a transient broad peak which indicates formation of the desired transition state model compound was observed in the laser flash photolytic study.
创建时间：
2016-05-06
