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Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2–Csp3 Bonds and Subsequent Competition between Csp2–H and Csp3–H Bond Activation

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Reductive_Elimination_from_Cyclometalated_Platinum_IV_Complexes_To_Form_C_sub_sp_sup_2_sup_sub_C_sub_sp_sup_3_sup_sub_Bonds_and_Subsequent_Competition_between_C_sub_sp_sup_2_sup_sub_H_and_C_sub_sp_sup_3_sup_sub_H_Bond_Activation/2511286
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Reductive elimination reactions of the cyclometalated platinum­(IV) compounds [PtMe2Br­{C6H4CHNCH2(4-ClC6H4)}­L] (L = SMe2, PPh3) to form Csp3–Csp2 bonds, followed by either exclusive Csp2–H bond activation (L = SMe2) or competition between Csp2–H and Csp3–H bond activation (L = PPh3) are reported. Reductive elimination to form a C–Br bond is also reported.
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2016-02-20
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