Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2–Csp3 Bonds and Subsequent Competition between Csp2–H and Csp3–H Bond Activation
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Reductive elimination reactions of the cyclometalated platinum(IV) compounds [PtMe2Br{C6H4CHNCH2(4-ClC6H4)}L] (L = SMe2, PPh3) to form Csp3–Csp2 bonds, followed by either exclusive Csp2–H bond activation (L = SMe2) or competition between Csp2–H and Csp3–H bond activation (L = PPh3) are reported. Reductive elimination to form a C–Br bond is also reported.
创建时间：
2016-02-20
