Dinuclear [CoII(NCMe)5CoII(NCS)4] Possessing Octahedral and Tetrahedral CoII Sites
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Dinuclear_Co_sup_II_sup_NCMe_sub_5_sub_Co_sup_II_sup_NCS_sub_4_sub_Possessing_Octahedral_and_Tetrahedral_Co_sup_II_sup_Sites/2589016
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The structural and magnetic properties of dinuclear [CoII(NCMe)5CoII(NCS)4]·MeCN have been investigated. The structure consists of an octahedral CoII(NCMe)5 center connected to a tetrahedral CoII(NCS)4 center bridged by a μ1,3-NCS– ligand. The bridging NCS– weakly couples the pair of S = 3/2 CoII spin sites, as evidenced by the magnetic data being best fit by the Curie–Weiss expression with θ = −15.5 K.
创建时间：
2016-02-22
