Diels−Alder Approach to Tetra-ortho-Substituted Biaryls Employing Propargylic Tertiary Alcohols as Dienophiles
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Diels_Alder_Approach_to_Tetra_ortho_Substituted_Biaryls_Employing_Propargylic_Tertiary_Alcohols_as_Dienophiles/2967280
下载链接
链接失效反馈官方服务：
资源简介：
The efficient synthesis of a series of tetra-ortho-substituted
biaryls is described utilizing a Diels−Alder reaction between
propargylic tertiary alcohols and cyclic oxygenated dienes.
The successful resolution of one of the biaryls is achieved
through derivatization with menthyl chloroformate followed
by crystallization. The menthyl carbamate is cleaved under
basic conditions to reveal enantiomerically pure biaryl
compounds.
创建时间：
2007-12-21
