Regioselective Tandem Dimethylsulfonium Methylide Addition−Eliminative Olefination of Diendioates: A Novel Route to 1,3-Butadien-2-ylmalonates
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The appropriate choice of dimethylsulfonium methylide generation conditions enables the highly regioselective tandem ylide addition−eliminative olefination to 1,3-dienedioates providing 1,3-butadien-2-ylmalonates, a novel class of 2-substituted 1,3-dienes suitable for quick assembly of precursors for type 2 intramolecular Diels−Alder reactions.
创建时间:
2016-06-03



