Transformation of a Metal−Organic Framework from the NbO to PtS Net
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Two metal−organic frameworks (MOFs), MOF-501 and MOF-502, respectively, formulated as Co2(BPTC)(H2O)5·Gx and Co2(BPTC)(H2O)(DMF)2·Gx (BPTC = 3,3‘,5,5‘-biphenyltetracarboxylate; G = guest molecules), have been synthesized and structurally characterized, and their topologies were found to be based on the NbO (MOF-501) and PtS (MOF-502) nets. Heating MOF-501 in solution results in the more thermodynamically favored MOF-502.
创建时间：
2005-01-24
