Auto-Tandem Palladium Catalysis: From Isoxazole to 2‑Azafluorenone
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https://figshare.com/articles/dataset/Auto_Tandem_Palladium_Catalysis_From_Isoxazole_to_2_Azafluorenone/2106874
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资源简介:
An auto-tandem palladium catalysis
from halogen-substituted isoxazoles
and Michael acceptors is described. It involves two mechanistically
distinct palladium-catalyzed reactions, a Heck reaction and a rearrangement,
leading to 2-azafluorenones. It is the first example of palladium-catalyzed
ring opening of isoxazoles and rearrangement of the β-imino
ketone ring-opening product.
创建时间:
2016-02-12



