Data for paper: Reduction of hexaazatrinaphthylenes by divalent lanthanocenes leads to ligand-based multiconfigurational properties
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资源简介：
<strong>Data for paper published in Dalton Transactions, 2024.</strong>
Data files for NMR spectra, IR spectra, UV/vis/NIR spectra and magnetism data. The zip files contain .xlsx, .cif, .dat and .fid files. .fids can be opened with NMR .fid processing software
<strong>Abstract</strong>
Reduction of hexaazatrinaphthylene (HAN) and its hexamethyl derivative with [Cp*<sub>2</sub>Sm(THF)<sub>2</sub>] or [Cp*<sub>2</sub>Yb(OEt<sub>2</sub>)] produces [(Cp*<sub>2</sub>Ln)<sub>3</sub>(R<sub>6</sub>HAN)] (Ln = Sm, Yb; R = H, Me), where the heterocyclic ligand forms as a trianion. The magnetism and electronic structure of these compounds reflect unusual multiconfigurational character within the reduced ligand but not the lanthanide ions.
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提供机构：
University of Sussex
创建时间：
2024-07-12
