Structure of a Novel Rhodium Phosphinite Compound: Agostic Interactions as a Model for an Oxidative Addition Intermediate
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Pincer ligand metalation is presumed to proceed via initial coordination to the phosphorus atoms followed by C–H oxidative addition. Few isolated intermediates in this process are known. A rhodium phosphinite complex has been isolated and structurally characterized that exhibits a strong agostic interaction with a C–H bond in the ligand backbone. The [(tBuPOCOP)Rh(CO)H]+ system exhibits greater acidity and reactivity than the analogous iridium species (tBuPOCOP = κ3-C6H3-1,3-[OP(tBu)2]2).
创建时间：
2016-06-21
