Gold-Catalyzed Atom-Economic Synthesis of Sulfone-Containing Pyrrolo[2,1‑a]isoquinolines from Diynamides: Evidence for Consecutive Sulfonyl Migration
收藏Figshare2019-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Gold-Catalyzed_Atom-Economic_Synthesis_of_Sulfone-Containing_Pyrrolo_2_1_i_a_i_isoquinolines_from_Diynamides_Evidence_for_Consecutive_Sulfonyl_Migration/7748726
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资源简介：
A gold-catalyzed cascade reaction of conjugated diynamides has been developed. In this way, a series of sulfone-containing pyrrolo[2,1-a]isoquinolines featuring the core structural motifs of lamellarin alkaloids were prepared atom economically. Mechanistic studies including DFT calculations uncovered a consecutive 1,2-migration of the sulfonyl group for the formation of a pyrrole ring.
创建时间：
2019-02-20
