Supramolecular Control of a Fast and Reversible Diels−Alder Reaction
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https://figshare.com/articles/dataset/Supramolecular_Control_of_a_Fast_and_Reversible_Diels_Alder_Reaction/2902519
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资源简介：
A new cyclophane featuring two opposite anthracene units linked in 9,10-positions has been synthesized thanks to the template effect of the Me4N+ ion. It forms pseudorotaxane complexes with alkylviologen ions and undergoes a fast and reversible reaction with tetracyanoethylene. A quantitative analysis has been carried out of the formation of Diels−Alder adducts, whose distribution can be controlled by host−guest complexation. These findings open interesting perspectives in the field of Dynamic Covalent Chemistry.
创建时间：
2016-02-27
