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Noncovalent Trapping and Stabilization of Dinuclear Ruthenium Complexes within a Coordination Cage

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https://figshare.com/articles/dataset/Noncovalent_Trapping_and_Stabilization_of_Dinuclear_Ruthenium_Complexes_within_a_Coordination_Cage/2623008
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资源简介:
A dinuclear ruthenium complex, [(η5-indenyl)Ru(CO)2]2, was noncovalently enclathrated within a self-assembled coordination cage. In the cavity, rapid cis–trans isomerization and ligand exchange between the terminal and bridging carbonyls were suppressed, and only the carbonyl-bridged cis configuration was observed by X-ray crystallographic analysis.
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2011-08-17
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