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Boosting the Nucleophilicity of Phosphole Lone Pairs by Isomerization

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NIAID Data Ecosystem2026-03-06 收录
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The phosphole isomer 4c can be obtained by nickelocene reduction complexation from the corresponding sulfide. It displays a ligating ability comparable to that of tris-tert-butylphosphine, and its [LPdCl2]2 complex efficiently catalyzes the deboronation homocoupling of arylboronic acids.

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2010-11-08
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