Oxygen Insertion of o‑Quinone under Catalytic Hydrogenation Conditions
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An oxygen-insertion reaction that transforms an o-quinone and a conjugated α-diketone substrate into an anhydride product or derivative under catalytic hydrogenation conditions is reported. The experiments and computations indicate that the oxygen insertion proceeds via a radical mechanism mediated by an acetoxyl radical.
创建时间：
2016-02-19
