Chiral Lewis Acid-Catalyzed Highly Enantioselective [4 + 3] Cycloaddition Reactions of Nitrogen-Stabilized Oxyallyl Cations Derived from Allenamides
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https://figshare.com/articles/dataset/Chiral_Lewis_Acid_Catalyzed_Highly_Enantioselective_4_3_Cycloaddition_Reactions_of_Nitrogen_Stabilized_Oxyallyl_Cations_Derived_from_Allenamides/3305050
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资源简介:
A chiral Lewis acid-catalyzed highly enantioselective [4 + 3] cycloaddition reaction of allenamide-derived nitrogen-stabilized chiral oxyallyl cations is described here. The use of bisoxazoline ligand and CuOTf2 provides high enantioselectivity, especially with [SbF6]- as the counteranion.
创建时间:
2016-05-06



