Synthesis and Structural Features of Co(II) and Co(III) Complexes Supported by Aminotrisphenolate Ligand Scaffolds
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Features_of_Co_II_and_Co_III_Complexes_Supported_by_Aminotrisphenolate_Ligand_Scaffolds/2240299
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资源简介：
Co(II) complexes
of aminotrisphenolate ((ArO)3N3–) ligands
can be prepared straightforwardly in high yield. X-ray analysis reveals
these complexes to comprise of two different hemispheres, one containing
an anionic Co((ArO)3N)− and the other
a cationic (ArO)3NH+ unit, which are associated
through hydrogen bonding. These Co(II) complexes can be easily converted
into their Co(III) analogues in air in the presence of suitable bases
such as dimethylaminopyridine and 2,2′-bipyridine, and the
structural features and magnetic properties of these latter compounds
are also reported.
创建时间：
2016-02-16
