A Supramolecular Heteropolyoxopalladate {Pd15} Cluster Host Encapsulating a {Pd2} Dinuclear Guest: [PdII2⊂{H7PdII15O10(PO4)10}]9−
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https://figshare.com/articles/dataset/A_Supramolecular_Heteropolyoxopalladate_Pd_sub_15_sub_Cluster_Host_Encapsulating_a_Pd_sub_2_sub_Dinuclear_Guest_Pd_sup_II_sup_sub_2_sub_H_sub_7_sub_Pd_sup_II_sup_sub_15_sub_O_sub_10_sub_PO_sub_4_sub_sub_10_sub_sup_9_sup_/2669041
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A high-nuclearity polyoxopalladate compound, [PdII2⊂{H7PdII15O10(PO4)10}]9− {PdII17}, comprising a {Pd15} host occupied by a {Pd2} guest and the parent pristine “empty” [H7PdII15O10(PVO4)10]13− {Pd15} cluster have both been prepared and characterized by single-crystal X-ray crystallography, 31P NMR, CSI-MS, and XPS. The encapsulated {Pd2} has a short PdII−PdII distance within the {Pd15} host. Solution studies indicate that the empty host and filled guest complex are in equilibrium with each other, and UV titrations revealed a binding constant of ca. 103 for the guest PdII ions, with a binding stoichiometry of almost 2.
创建时间：
2016-02-23
