Cinchona Alkaloid Amides/Dialkylzinc Catalyzed Enantioselective Desymmetrization of Aziridines with Phosphites
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https://figshare.com/articles/dataset/Cinchona_Alkaloid_Amides_Dialkylzinc_Catalyzed_Enantioselective_Desymmetrization_of_Aziridines_with_Phosphites/2465242
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资源简介：
The first highly enantioselective desymmetrization of
aziridines
with phosphites has been developed. Excellent yields and enantioselectivities
were observed for the reaction with various aziridines using a new
class of readily accessible chiral catalysts derived from 9-amino-9-deoxy-epi-cinchona alkaloids. In studies probing the reaction
mechanism, we observed some complexes for the cinchona alkaloid amide-Zn(II)
by ESI-MS analysis.
创建时间：
2012-11-28
