Synthesis, Structures, and Catalytic Properties of Late-Transition-Metal 2,6-Bis(2-phosphaethenyl)pyridine Complexes
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https://figshare.com/articles/dataset/Synthesis_Structures_and_Catalytic_Properties_of_Late-Transition-Metal_2_6-Bis_2-phosphaethenyl_pyridine_Complexes/12066489
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资源简介:
2,6-Bis(2-phosphaethenyl)pyridine (PNP) complexes
of Rh(I), Cu(I), and Ag(I) have been prepared and examined
by NMR and X-ray diffraction analyses. The PNP ligand adopts
κ3(P,N,P) coordination for Rh(I) and Cu(I) and κ2(P,P)
coordination for Ag(I). The rhodium complex [RhCl(PNP)] in
combination with AgOTf catalyzes conjugate addition of benzyl
carbamate to enones.
创建时间:
2007-10-08



