One-Pot Conversion of Fluorophores to Phosphorophores
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https://figshare.com/articles/dataset/One-Pot_Conversion_of_Fluorophores_to_Phosphorophores/4220658
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资源简介：
Facile, one-pot conversion of free
base 5,10,15-tris(pentafluorophenyl)corrole,
(H3)tpfc, into the coinage metal complexes of 2,3,17,18-tetraiodo-5,10,15-tris(pentafluorophenyl)corrole,
(I4-tpfc)M (M = Cu, Ag, Au), is reported. The iodination/metalation
procedures provide much higher yields and larger selectivity than
both conceivable stepwise syntheses. Photophysical analysis shows
that the gold(III) complex (I4-tpfc)Au displays phosphorescence
at room temperature and a substantial quantum yield for singlet oxygen
formation.
创建时间：
2016-11-14
