Silver-Catalyzed Difluoroamidation of Activated Alkenes for the Construction of Difluorinated 3,3-Disubstituted Oxindoles
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https://figshare.com/articles/dataset/Silver-Catalyzed_Difluoroamidation_of_Activated_Alkenes_for_the_Construction_of_Difluorinated_3_3-Disubstituted_Oxindoles/3458270
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资源简介：
A AgOAc catalyzed difunctionalization
of activated alkenes through
a difluoroamidic radical addition to afford difluoroamidated 3,3-disubstituted
oxindoles has been developed. Various functional groups were well
tolerated. Moreover, the product could be efficiently derived to the
corresponding difluorofunctionalized alcohol, ketone, and ester in
high yields. The mechanistic studies revealed that a radical pathway
was involved in the transformation.
创建时间：
2016-06-27
