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Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Aerobic_and_Ligand-Free_Manganese-Catalyzed_Homocoupling_of_Arenes_or_Aryl_Halides_via_in_Situ_Formation_of_Aryllithiums/7838003
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Ligand-free manganese-catalyzed homocoupling of arenes or aryl halides can be carried out under aerobic conditions via the in situ formation of the corresponding aryllithiums. A wide range of biaryls and derivatives has been obtained, and a mechanism involving monomeric manganese-oxo complexes has been proposed on the basis of DFT calculations.
创建时间:
2019-03-13
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