High-Spin and Spin-Crossover Behavior in Monomethylated Bis(indenyl)chromium(II) Complexes

Previous work on bis(indenyl)chromium(II) complexes substituted with bulky groups (i-Pr, t-Bu, SiMe3)
found that their spin state (S = 1 or 2) depended on the symmetry of the molecules. Complexes with
inversion symmetry (staggered rings) were high-spin; lower symmetry compounds with twisted (gauche)
ligands were low spin. The present work explores the effect of methyl group substitution on the indenyl
ligand, which leads to complexes possessing either staggered or eclipsed conformations. The monosubstituted compounds [(1 or 2)-MeC9H6]2Cr are prepared from the substituted alkali metal indenides and
CrCl2 in THF. X-ray diffraction results indicate that (2-MeC9H6)2Cr exists in a staggered conformation,
with Cr−C (av) = 2.308(7) Å, and is a high-spin species in the solid state and solution. In contrast, the
monomeric (1-MeC9H6)2Cr is eclipsed in the solid state, where it exhibits spin-crossover behavior over
a wide temperature range; the average Cr−C distances vary with temperature, from 2.179(9) Å at 105 K
to 2.262(10) Å at 298 K. An attempt to form (4-MeC9H6)2Cr produced the dimeric, thermally unstable
complex (η5-indenyl‘)2(μ,η3-indenyl‘)Cr2(μ-Cl) instead. Correlations between the structure and magnetic
properties in bis(indenyl)chromium(II) complexes have been made with density functional theory
calculations, which indicate that an eclipsed ligand conformation supports a high spin state, but not to
the extent that the staggered form does.