Rhodium(II)-Catalyzed Stereocontrolled Synthesis of Dihydrofuran-3-imines from 1‑Tosyl-1,2,3-triazoles
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下载链接：
https://figshare.com/articles/dataset/Rhodium_II_Catalyzed_Stereocontrolled_Synthesis_of_Dihydrofuran_3_imines_from_1_Tosyl_1_2_3_triazoles/2313052
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资源简介：
Rhodium(II) acetate catalyzes the
denitrogenative transformation
of 5-substituted and 4,5-disubstituted 1-sulfonyl-1,2,3-triazoles
with pendent allyl and propargyl ether motifs to oxonium ylides that
undergo [2,3]-sigmatropic rearrangement to give substituted dihydrofuran-3-imines
in high yield and diastereoselectivity.
创建时间：
2017-06-08
