Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether
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https://figshare.com/articles/dataset/Trifluoromethyl_Substituted_Sulfonium_Ylide_Rh_Catalyzed_Carbenoid_Addition_to_Trifluoromethylthioether/2161249
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资源简介:
A highly efficient Rh-catalyzed carbenoid addition to trifluoromethylthioether for the formation of trifluoromethyl-substituted sulfonium ylide is described. The trifluoromethyl-substituted sulfonium ylide can act as an electrophilic trifluoromethylation reagent, as demonstrated by trifluoromethylation of β-ketoesters and aryl iodides.
创建时间:
2016-02-13



