The crystal structures of coordinatively unsaturated [(TpNpCo)2(μ-N2)] and TpNpCo(CO) show “bent” molecules, in which the fourth ligand (N2, CO) is bent away from the pseudo-threefold axis of the TpCo
Herein, we report the synthesis, structural investigation, and magnetic and photophysical properties of a series of 13 [ZnIILnIII] heterodinuclear complexes, which have been obtained employing a Schif
The reaction of 9-{[N-n-propyl-N-(diphenylphosphino)amino]methyl}anthracene (1) with Au(SMe2)Cl yields complex 2 with an arm-opening configuration. The latter is treated with AgClO4 to form complex 4
Despite the prevalence of stable π-complexes of most d10 metals, such as Cu(I) and Ni(0), with ethylene and other olefins, complexation of d10 Zn(II) to simple olefins is too weak to form isolable c