Nickel-Catalyzed Decarbonylation of Acylsilanes
收藏Figshare2020-04-28 更新2026-04-28 收录
下载链接：
https://figshare.com/articles/dataset/Nickel-Catalyzed_Decarbonylation_of_Acylsilanes/12290678
下载链接
链接失效反馈官方服务：
资源简介：
Nickel-catalyzed decarbonylation of acylsilanes is developed. In sharp contrast to cross-coupling reactions of acylsilanes, in which the silyl group serves as a leaving group, the silyl group is retained in the product in this decarbonylation reaction. Although the strong binding of the dissociated CO to the nickel center frequently hinders catalyst turnover in nickel-mediated decarbonylative reactions, this reaction can be catalyzed by nickel complexes bearing a CO ligand.
创建时间：
2020-04-28
