A Convenient One-Pot Synthesis of a Functionalized-Arene Ruthenium Half-Sandwich Compound [RuCl<sub>2</sub>(η<sup>6</sup>-C<sub>6</sub>H<sub>5</sub>OCH<sub>2</sub>CH<sub>2</sub>OH)]<sub>2</sub>
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Reaction of RuCl3·xH2O with 1-methoxy-1,4-cyclohexadiene in an alcohol solvent, ROH, gives [RuCl2(η6-C6H5OR)]2 (R = Me, Et, or HOCH2CH2) in up to 79% yield. The crystal structures of [Ru2(μ-Cl3)(η6-C6H5OEt)2]+[BPh4]- and [RuCl2(η6-C6H5OCH2CH2OH)]2 are also reported.
创建时间:
2016-05-06



