Flux Growth of Yb6.6Ir6Sn16 Having Mixed-Valent Ytterbium
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https://figshare.com/articles/dataset/Flux_Growth_of_Yb_sub_6_6_sub_Ir_sub_6_sub_Sn_sub_16_sub_Having_Mixed_Valent_Ytterbium/2276620
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The compound Yb6.6Ir6Sn16 was obtained as single crystals in high yield from the reaction of Yb with Ir and Sn run in excess indium. Single-crystal X-ray diffraction analysis shows that Yb6.6Ir6Sn16 crystallizes in the tetragonal space group P42/nmc with a = b = 9.7105(7) Å and c = 13.7183(11) Å. The crystal structure is composed of a [Ir6Sn16] polyanionic network with cages in which the Yb atoms are embedded. The Yb sublattice features extensive vacancies on one crystallographic site. Magnetic susceptibility measurements on single crystals indicate Curie–Weiss law behavior B/Yb, which is ∼70% of the expected value for a free Yb3+ ion suggesting the presence of mixed-valent ytterbium atoms. X-ray absorption near edge spectroscopy confirms that Yb6.6Ir6Sn16 exhibits mixed valence. Resistivity and heat capacity measurements for Yb6.6Ir6Sn16 indicate non-Fermi liquid metallic behavior.
创建时间：
2016-02-17
