[Ru4(CO)8(μ-OOCCH2CH3)4(THF)2] and [Ru3(μ3‑OH)(CO)6(μ-OOCtBu)4(OOCtBu)]: Novel Multinuclear Ruthenium Carbonyl Carboxylates
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https://figshare.com/articles/dataset/_Ru_sub_4_sub_CO_sub_8_sub_OOCCH_sub_2_sub_CH_sub_3_sub_sub_4_sub_THF_sub_2_sub_and_Ru_sub_3_sub_sub_3_sub_OH_CO_sub_6_sub_OOC_sup_i_t_i_sup_Bu_sub_4_sub_OOC_sup_i_t_i_sup_Bu_Novel_Multinuclear_Ruthenium_Carbonyl_Carboxylates/2562751
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资源简介：
The reaction of Ru3(CO)12 with pivalic or propionic acid leads to the formation of two novel multinuclear ruthenium complexes, [Ru4(CO)8(μ-OOCCH2CH3)4(THF)2] (1) and [Ru3(μ3-OH)(CO)6(μ-OOCtBu)4(OOCtBu)] (2). Compound 1 is among the few examples of discrete tetranuclear ruthenium compounds showcasing a “dimer of dimers” paddlewheel structure, in which two “Ru2(CO)4(μ-OOCCH2CH3)2(THF)” fragments are linked via Ru–O interactions. Compound 2 features a unique structural motif in which a triangular Ru3 core is connected via a μ3-OH ligand.
创建时间：
2016-02-22
