Designer Discodermolide Segments via Ozonolysis of Vinyl Phosphonates
收藏NIAID Data Ecosystem2026-03-06 收录
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To apply our collection of enantiopure 7-ring vinyl sulfones to probe the anticancer SAR of a series of computer-designed (+)-discodermolide analogs, the ozonolytic reactivity of transposed cyclic vinyl phosphonates was explored. Successful preparation of the desired aldehyde-esters and lactones from vinyl phosphonates via an oxidative cleavage−phosphite/methanol exchange sequence is described.
创建时间：
2009-02-05
