Organocatalytic Enantioselective Formal C(sp<sup>2</sup>)–H Alkylation
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
An organocatalytic enantioselective formal C(sp2)–H alkylation is reported. This alkylative desymmetrization of prochiral 2,2-disubstituted cyclopentene-1,3-dione is catalyzed by a bifunctional tertiary aminourea derivative, utilizes air-stable and inexpensive nitroalkanes as the alkylating agents, and delivers synthetically versatile five-membered carbocycles containing an all-carbon quaternary stereogenic center remote from the reaction site in excellent enantioselectivity.
创建时间：
2015-01-14
