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Palladium-Catalyzed Enantioselective Desymmetrization of Silacyclobutanes: Construction of Silacycles Possessing a Tetraorganosilicon Stereocenter

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Enantioselective_Desymmetrization_of_Silacyclobutanes_Construction_of_Silacycles_Possessing_a_Tetraorganosilicon_Stereocenter/2599900
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A palladium-catalyzed desymmetrization of alkyne-tethered silacyclobutanes to give silacycles possessing a tetraorganosilicon stereocenter has been developed, and high chemo- and enantioselectivities have been achieved by the use of a newly synthesized chiral phosphoramidite ligand.
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2016-02-22
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