Planar Discrimination in an SPS-Based Rhodium(I) Complex
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https://figshare.com/articles/dataset/Planar_Discrimination_in_an_SPS_Based_Rhodium_I_Complex/3360367
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资源简介：
This work describes the reactivity of the SPS-type pincer-based RhI complex 4 toward CO, O2, CO2,
CS2, and SO2 to afford the corresponding RhI or RhIII
adducts. The SPS ligand is able to adopt a facial
coordination mode in these trigonal-bipyramidal complexes. Differentiation of the two faces of the square-planar RhI complex 4 could be rationalized by a mechanical effect due to the rigidity of the central phosphinine
backbone.
创建时间：
2016-05-07
