Stereoselective Construction of Bridged trans-aza-Bicyclo[7/6,3/2,1]alkenyl Imines through Ring Expansion aza-Cope Rearrangement
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https://figshare.com/articles/dataset/Stereoselective_Construction_of_Bridged_i_trans_i_aza_Bicyclo_7_6_3_2_1_alkenyl_Imines_through_Ring_Expansion_aza_Cope_Rearrangement/2106892
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资源简介：
A highly stereoselective method for efficient synthesis of unprecedented bridged bicyclo[7/6,3/2,1]alkenyl amidines is described using cyclic N-allyl-aminoalkyne as a substrate. A ketenimine formation/cyclization/aza-Cope rearrangement cascade proceeds either with or without the aid of external DIPEA depending on substrate basicity. Fused bicycloamidines are also obtained via the same protocol using different N-allyl cyclic aminoalkynes.
创建时间：
2016-02-12
