Iridium-Catalyzed Enantioselective Allylic Substitution of <i>O</i>-Allyl Carbamothioates
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With an [Ir(COD)Cl]2/phosphoramidite ligand system, an allylic substitution of O-allyl carbamothioates was developed. The reaction proceeded in the favor of branched products with up to 93:7 branched-to-linear ratio, affording chiral S-allyl carbamothioates with up to 95% ee.
创建时间：
2010-07-02
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