X-ray Absorption Spectroscopic Studies on Light-Induced Excited Spin State Trapping of an Fe(II) Complex
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https://figshare.com/articles/dataset/X-ray_Absorption_Spectroscopic_Studies_on_Light-Induced_Excited_Spin_State_Trapping_of_an_Fe_II_Complex/3678675
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资源简介：
Light-induced excited spin state trapping of Fe(phen)2(NCS)2 is studied by X-ray absorption
spectroscopy using synchrotron radiation. The molecular structure of the excited high-spin state at 17 K is
investigated by EXAFS. The relaxation of the light-induced high-spin state at various temperatures is monitored
through the absorption spectra. The concurrent abrupt lattice change with the change in electronic configuration
is observed through single crystal X-ray diffraction. The lattice cooperative effect is important in the relaxation
behavior. The magnetic property and the relaxation behavior of two differently prepared samples are distinctly
different.
创建时间：
2016-08-19
