Synthesis and Reactivity of the Carbaalanes (AlH)<sub>6</sub>(AlNMe<sub>3</sub>)<sub>2</sub>(CCH<sub>2</sub>C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)<sub>6</sub> and (AlH)<sub>6</sub>(AlNMe<sub>3</sub>)<sub>2</sub>(CCH<sub>2</sub>Ph)<sub>6</sub>: X-ray Crystal Structure of (AlH)<sub>6</sub>(AlNMe<sub>3</sub>)<sub>2</sub>(CCH<sub>2</sub>C<sub>5</sub>H<sub>4</sub>FeC<sub>5</sub>H<sub>5</sub>)<sub>6</sub><sup>†</sup>
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数据链接：
https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_the_Carbaalanes_AlH_sub_6_sub_AlNMe_sub_3_sub_sub_2_sub_CCH_sub_2_sub_C_sub_5_sub_H_sub_4_sub_FeC_sub_5_sub_H_sub_5_sub_sub_6_sub_and_AlH_sub_6_sub_AlNMe_sub_3_sub_sub_2_sub_CCH_sub_2_sub_Ph_sub_6_sub_X_ray_Crystal_Structure_of/3333544数据链接链接失效反馈
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资源简介：
The synthesis of the aluminum carbide clusters (AlH)6(AlNMe3)2(CCH2C5H4FeC5H5)6 (1), containing an assembly of ferrocenylmethylene substituents, and (AlH)6(AlNMe3)2(CCH2Ph)6 (2) was carried out by the hydroalumination of FcC⋮CH (Fc = ferrocenyl) and (PhC⋮C)3Al·NMe3, respectively, with AlH3·NMe3. Compound 1 is made up of an Al−C framework with eight aluminum atoms occupying the corners of a rhombic cube while the six carbon atoms cap the faces of the cube. The reaction of (AlH)6(AlNMe3)2(CCH2Ph)6 (2) with FcC⋮CH and PhC⋮CH leads to the formation of (AlH)2(FcC⋮CAl)4(AlNMe3)2(CCH2Ph)6 (3) and (PhC⋮C)3Al·NMe3 (4), respectively. Reaction of 4 with AlH3·NMe3 results in the formation of 2.
创建时间：
2016-05-06
