Synthesis and Alkyne Insertion Reactions of NHC-Based Cyclometalated Ruthenium(II) Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Alkyne_Insertion_Reactions_of_NHC_Based_Cyclometalated_Ruthenium_II_Complexes/2246299
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资源简介：
The series of NHC-based cyclometalated
ruthenium(II) complexes 2a–k were
synthesized by the reactions of aryl-substituted imidazolium salts
with [(p-cymene)RuCl2]2 under
mild conditions. These complexes could react with alkynes in MeOH
at 80 °C, through alkyne insertion and subsequent reductive elimination,
to give the new kinds of imidazolium salts 3a–q in high yields. All new compounds were fully characterized,
and the molecular structures of 2a–d,f,g,i–k were determined by single-crystal X-ray diffraction analysis.
创建时间：
2016-02-16
