Lewis Acid Catalyzed Formal Intramolecular [3 + 3] Cross-Cycloaddition of Cyclopropane 1,1-Diesters for Construction of Benzobicyclo[2.2.2]octane Skeletons
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https://figshare.com/articles/dataset/Lewis_Acid_Catalyzed_Formal_Intramolecular_3_3_Cross_Cycloaddition_of_Cyclopropane_1_1_Diesters_for_Construction_of_Benzobicyclo_2_2_2_octane_Skeletons/2200327
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资源简介：
A novel Lewis acid catalyzed formal
intramolecular [3 + 3] cross-cycloaddition
(IMCC) of cyclopropane 1,1-diesters has been successfully developed.
This supplies an efficient and conceptually new strategy for construction
of bridged bicyclo[2.2.2]octane skeletons. This [3 + 3]IMCC could
be run up to gram scale and from easily prepared starting materials.
This [3 + 3]IMCC, together with our previously reported [3 + 2]IMCC
strategy, can afford either the bicyclo[2.2.2]octane or bicyclo[3.2.1]octane
skeletons from the similar starting materials by regulating the substituents
on vinyl group.
创建时间：
2016-02-15
