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Isolation of 6,13-Dipropylpentacene and Its Tautomerization

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NIAID Data Ecosystem2026-03-06 收录
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6,13-Dipropyl-5,14-dihydropentacene was aromatized by the combination of the formation of pentacene-DDQ adduct and abstraction of DDQ from the pentacene-DDQ adduct with 50 equiv of γ-terpinene to give 6,13-dipropylpentacene cleanly. It was stable and isolable. In the presence of a catalytic amount of acid, 6,13-dipropylpentacene was isomerized to its tautomer.

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2016-06-03
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