Synthesis and Characterization of Neutral and Cationic Intramolecularly Coordinated Aluminum Compounds. Structural Determination of [(Pytsi)AlMe]<sup>+</sup>[MeB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>]<sup>-</sup> [(Pytsi = C(SiMe<sub>3</sub>)<sub>2</sub>SiMe<sub>2</sub>(2-C<sub>5</sub>H<sub>4</sub>N)]
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Neutral_and_Cationic_Intramolecularly_Coordinated_Aluminum_Compounds_Structural_Determination_of_Pytsi_AlMe_sup_sup_MeB_C_sub_6_sub_F_sub_5_sub_sub_3_sub_sup_sup_Pytsi_C_SiMe_sub_3_sub_sub_2_sub_SiMe_sub_2_sub_2_C_sub_5_s/3253480数据链接链接失效反馈
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资源简介：
The synthesis and structure of neutral and cationic aluminum compounds equipped with the intramolecular donating C(SiMe3)2SiMe2(2-C5H4N) ligand denoted by Pytsi is described. The compounds (Pytsi)AlMe2 (1), (Pytsi)AlEt2 (2), [(Pytsi)AlMe]+[MeB(C6F5)3]- (3), and [(Pytsi)AlMe(thf)]+[MeB(C6F5)3]- (3·thf) have been synthesized and characterized by standard methods, and the molecular structures of 1, 2, and 3 have been determined by single-crystal X-ray analyses. Compound 3 was obtained by an addition of 1 equiv of B(C6F5)3 to the dimethyl species 1. The salt-like title compound 3 shows a methyl group in a bridging position between Al and B atoms consisting of a long Al−C distance of 2.380(2) Å and a B−C bond length of 1.681(3) Å.
创建时间：
2016-05-05
