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MacDonald-Type Reactions Using Bis-acrylaldehydes: Synthesis of an Expanded Sapphyrin and Vinylogous Hexaphyrins

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https://figshare.com/articles/dataset/MacDonald_Type_Reactions_Using_Bis_acrylaldehydes_Synthesis_of_an_Expanded_Sapphyrin_and_Vinylogous_Hexaphyrins/2870416
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资源简介:
Acid-catalyzed condensations between a dipyrrylmethane and a pyrrole bisacrylaldehyde gave an unusual stretched sapphyrin structure together with a hexaphyrin byproduct. A diazulihexaphyrin was prepared similarly. The highly diatropic sapphyrin analogue was isolated as a dication and was characterized by X-ray crystallography.
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2016-02-26
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