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Palladium-Catalyzed Asymmetric C–H Arylation for the Synthesis of Planar Chiral Benzothiophene-Fused Ferrocenes

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https://figshare.com/articles/dataset/Palladium-Catalyzed_Asymmetric_C_H_Arylation_for_the_Synthesis_of_Planar_Chiral_Benzothiophene-Fused_Ferrocenes/7339667
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资源简介:
An intramolecular enantioselective C–H arylation of ferrocenyl aryl sulfides was performed with a palladium catalyst. Planar chiral thiophene compounds with a ferrocene skeleton were constructed in good enantioselectivities (up to 99% ee) and high yields, and the utility of the obtained chiral sulfides as ligands in catalytic reactions has been demonstrated.
创建时间:
2018-11-14
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