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Ions at the Surface of a Room-Temperature Ionic Liquid

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https://figshare.com/articles/dataset/Ions_at_the_Surface_of_a_Room_Temperature_Ionic_Liquid/3004135
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The orientation and interfacial location of both the cation and anion of the ionic liquids 1-butyl-3-methylimidazolium methyl sulfate and 1-butyl-3-methylimidazolium methanesulfonate have been determined by sum-frequency generation vibrational spectroscopy and X-ray crystallography. The results indicate that both the cation and anion occupy the first layer at the gas−liquid interface. Further, the methyl groups of the cation and anion are directed away from the liquid phase into the gas phase.
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2007-05-31
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