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Synthesis and Structure of Corona[6](het)arenes Containing Mixed Bridge Units

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Corona_6_het_arenes_Containing_Mixed_Bridge_Units/3382621
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A one-pot nucleophilic aromatic substitution reaction of 3,6-dichlorotetrazine with various diphenols and dibenzenethiols produced corona[4]­arene[2]­tetrazines that contain mixed oxygen, sulfide, methylene, and sulfone linkages. Macrocyclic ring transformations employing an inverse-electron-demand Diels–Alder reaction of tetrazine moieties with enamines and the subsequent sulfide oxidation reaction afforded diverse corona[4]­arene[2]­pyridazines. The acquired corona[6]­arenes adopted three types of conformational structures in the crystalline state.
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2016-05-27
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